Cloud point extraction–Microvolume spectrophotometry for extraction and determination of bismuth in waters and roadside soil
The authors, in the present work, described a new microvolume spectrophotometric method for extraction, preconcentration and determination of extremely low quantities of bismuth in waters and roadside soil. The strategy of method is based on the formation of an ionic pair between [BiI4]− and trioctylamine [TOA]+ in aqueous phase and extraction of this ion associate by cloud point extraction technique (CPE) using Triton X-100. The influence of different empirical parameters e.g. pH of aqueous phase, surfactant concentration, equilibrium time and temperature on performance efficiency of developed method was studied and then optimized. On the optimum conditions, the absorbance of Triton X-100 – rich phase measured at 342 nm was linear with bismuth quantity in aqueous phase in the range of 10–1250 μg L− 1 with R = 0.996, n = 7. The limit of detection (LOD), quantitation (LOQ), and preconcentration factor …